Nanocarbons, such as fullerene (a sphere, for which the 1996 Nobel Prize was awarded), the carbon nanotube (a cylinder, discovered in 1991) and graphene (a sheet, for which the 2010 Nobel Prize was given) have attracted a great deal of attention as functional molecules with a variety of different properties. Since Mackay et al. put forward their theory in 1991, a variety of periodic three-dimensional nanocarbons have been proposed.

However, these have been extraordinarily difficult to synthesize. A particular challenge is the eight-membered ring structure, which appears periodically, necessitating an efficient method for its synthesis. To do so, Dr. Itami's research team developed a new method for connecting polycyclic aromatic hydrocarbons using a palladium catalyst to produce eight-membered rings via cross-coupling, the first reaction of its type in the world.

The success of this research represents a revolutionary achievement in three-dimensional nanocarbon molecule synthesis. It is expected to lead to the discovery and elucidation of further novel properties and the development of next-generation functional materials.

More information: Satoshi Matsubara et al, Creation of negatively curved polyaromatics enabled by annulative coupling that forms an eight-membered ring, Nature Catalysis (2020), DOI: 10.1038/s41929-020-0487-0.

Institute of Transformative Bio-Molecules (ITbM), Nagoya University. Accessed: August 07, 2020.

<< voltar para novidades