Laboratório de Química do Estado Sólido
 LQES NEWS  portfólio  em pauta | pontos de vista | vivência lqes | lqes cultural | lqes responde 
 o laboratório | projetos e pesquisa | bibliotecas lqes | publicações e teses | serviços técno-científicos | alunos e alumni 

LQES
lqes news
novidades de C&T&I e do LQES

2021

2020

2019

2018

2017

2016

2015

2014

2013

2012

2011

2010

2009

2008

2007

2006

2005

2004

2003

2002

2001

LQES News anteriores

em foco

hot temas

 
NOVIDADES

Nano-Saturn.


Saturn is the second largest planet in our solar system and has a characteristic ring. Japanese researchers have now synthesized a molecular “nano-Saturn”. As the scientists report in the journal Angewandte Chemie, ("Nano-Saturn: Experimental Evidence of Complex Formation of an Anthracene Cyclic Ring with C60") it consists of a spherical C60 fullerene as the planet and a flat macrocycle made of six anthracene units as the ring. The structure is confirmed by spectroscopic and X-ray analyses.

Nano-Saturn systems with a spherical molecule and a macrocyclic ring have been a fascinating structural motif for researchers. The ring must have a rigid, circular form, and must hold the molecular sphere firmly in its midst. Fullerenes are ideal candidates for the nano-sphere. They are made of carbon atoms linked into a network of rings that form a hollow sphere. The most famous fullerene, C60, consists of 60 carbon atoms arranged into 5- and 6-membered rings like the leather patches of a classic soccer ball. The electrons in their double bonds, knows as the Pi-electrons, are in a kind of “electron cloud”, able to freely move about and have binding interactions with other molecules, such as a macrocycle that also has a “cloud” of Pi-electrons. The attractive interactions between the electron clouds allow fullerenes to lodge in the cavities of such macrocycles.



Nano-Saturn - Supramolecular complex formation: Anthracene macrocycle and C60 fullerene.

© Wiley-VCH


A series of such complexes has previously been synthesized. Because of the positions of the electron clouds around the macrocycles, it was previously only possible to make rings that surround the fullerene like a belt or a tire. The ring around Saturn, however, is not like a “belt” or “tire”, it is a very flat disc. Researchers working at the Tokyo Institute of Technology and Okayama University of Science (Japan) wanted to properly imitate this at nanoscale.

Their success resulted from a different type of bonding between the “nano-planet” and its “nano-ring”. Instead of using the attraction between the Pi-electron clouds of the fullerene and macrocycle, the team working with Shinji Toyota used the weak attractive interactions between the π-electron cloud of the fullerene and non-Pi-electron of the carbon-hydrogen groups of the macrocycle.

To construct their “Saturn ring”, the researchers chose to use anthracene units, molecules made of three aromatic six-membered carbon rings linked along their edges. They linked six of these units into a macrocycle whose cavity was the perfect size and shape for a C60 fullerene. Eighteen hydrogen atoms of the macrocycle project into the middle of the cavity. In total, their interactions with the fullerene are enough to give the complex enough stability, as shown by computer simulations. By using X-ray analysis and NMR spectroscopy, the team was able to prove experimentally that they had produced Saturn-shaped complexes.


About the Author

Dr Shinji Toyota is professor at Tokyo Institute of Technology, Department of Chemistry, School of Science. His major research areas are physical organic chemistry, aromatic chemistry, supramolecular chemistry, and stereochemistry.

Science Daily. Posted: June 08, 2018.



<< voltar para novidades

 © 2001-2020 LQES - lqes@iqm.unicamp.br sobre o lqes | políticas | link o lqes | divulgação | fale conosco